A peroxynitrite complex of copper: formation from a copper–nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration

Reaction of nitrogen monoxide with a copper(I) complex possessing a tridentate alkylamine ligand gives a Cu(I)–(·NO) adduct, which when exposed to dioxygen generates a peroxynitrite (O=NOO(−))–Cu(II) species. This undergoes thermal transformation to produce a copper(II) nitrito (NO(2)(−)) complex an...

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Autores principales: Park, Ga Young, Deepalatha, Subramanian, Puiu, Simona C., Lee, Dong-Heon, Mondal, Biplab, Sarjeant, Amy A. Narducci, del Rio, Diego, Pau, Monita Y. M., Solomon, Edward I., Karlin, Kenneth D.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2009
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2908284/
https://ncbi.nlm.nih.gov/pubmed/19662443
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-009-0575-8
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