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Sulfur K-edge X-ray Absorption Spectroscopy and Density Functional Calculations on Mo(IV) and Mo(VI)=O Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in DMSO Reductase and Related Functional Analogues

Sulfur K-edge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations have been used to determine the electronic structures of two Mo bis-dithiolene complexes, [Mo(OSi)(bdt)(2)](1−) and [MoO(OSi)(bdt)(2)](1−) where OSi = [OSiPh(2)(t)Bu](1−) and bdt = benzene-1,2-dithiola...

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Dettagli Bibliografici
Autori principali: Tenderholt, Adam L., Wang, Jun-Jieh, Szilagyi, Robert K., Holm, Richard H., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2907113/
https://ncbi.nlm.nih.gov/pubmed/20499905
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910369c
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