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Sulfur K-edge X-ray Absorption Spectroscopy and Density Functional Calculations on Mo(IV) and Mo(VI)=O Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in DMSO Reductase and Related Functional Analogues
Sulfur K-edge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations have been used to determine the electronic structures of two Mo bis-dithiolene complexes, [Mo(OSi)(bdt)(2)](1−) and [MoO(OSi)(bdt)(2)](1−) where OSi = [OSiPh(2)(t)Bu](1−) and bdt = benzene-1,2-dithiola...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2907113/ https://ncbi.nlm.nih.gov/pubmed/20499905 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910369c |
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