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Sulfur K-Edge X-ray Absorption Spectroscopy and Density Functional Theory Calculations on Monooxo Mo(IV) and Bisoxo Mo(VI) Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in Sulfite Oxidase and Its Relation to the Mechanism of DMSO Reductase
[Image: see text] Sulfur K-edge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations have been used to determine the electronic structures of two complexes [Mo(IV)O(bdt)(2)](2–) and [Mo(VI)O(2)(bdt)(2)](2–) (bdt = benzene-1,2-dithiolate(2−)) that relate to the reduced...
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| Main Authors: | , , , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4073832/ https://ncbi.nlm.nih.gov/pubmed/24884723 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja503316p |
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