Manganese Catalysts for C–H activation: An Experimental/Theoretical Study Identifies the Stereoelectronic Factor that Controls the Switch between Hydroxylation and Desaturation Pathways

We describe competitive C–H activation chemistry of two types, desaturation and hydroxylation, using synthetic manganese catalysts with several substrates. 9,10-dihydrophenanthrene (DHP) gives the highest desaturation activity, the final products being phenanthrene (P1) and phenanthrene-9,10-oxide (...

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Detaylı Bibliyografya
Asıl Yazarlar: Hull, Jonathan F., Balcells, David, Sauer, Effiette L. O., Raynaud, Christophe, Brudvig, Gary W., Crabtree, Robert H., Eisenstein, Odile
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2010
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Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2903729/
https://ncbi.nlm.nih.gov/pubmed/20481432
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja908744w
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