The Crystal Structure of a High-Spin OxoIron(IV) Complex and Characterization of Its Self-Decay Pathway

[Fe(IV)(O)(TMG(3)tren)](2+) (1; TMG(3)tren = 1,1,1-tris{2-[N(2)-(1,1,3,3-tetramethylguanidino)]ethyl}amine) is a unique example of an isolable synthetic S = 2 oxoiron(IV) complex, which serves as a model for the high-valent oxoiron(IV) intermediates observed in nonheme iron enzymes. Congruent with D...

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Hlavní autoři: England, Jason, Guo, Yisong, Farquhar, Erik R., Young, Victor G., Münck, Eckard, Que, Lawrence
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2903234/
https://ncbi.nlm.nih.gov/pubmed/20568768
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja100366c
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