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Silylene oxonium ylides: di-tert-butylsilylene insertion into C—O bonds
[Image: see text] Allylic ethers undergo insertions of silylenes into C—O bonds to form allylic silanes. Silylene insertion into C—O acetal bonds was also observed. Formation of silylene ylide intermediates led to [1,2]-Stevens rearrangement products as well as [2,3]-sigmatropic products depending u...
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| Hlavní autoři: | , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2009
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2902782/ https://ncbi.nlm.nih.gov/pubmed/20631913 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.04.016 |
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