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Intermolecular Silacarbonyl Ylide Cycloadditions: A Direct Pathway to Oxasilacyclopentenes

[Image: see text] Silacarbonyl ylides, generated by metal-catalyzed silylene transfer to carbonyls, participate in formal intermolecular 1,3-dipolar cycloaddition reactions with carbonyl compounds and alkynes to form dioxasilacyclopentane acetals and oxasilacyclopentenes in an efficient, one-step pr...

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Détails bibliographiques
Auteurs principaux: Bourque, Laura E., Woerpel, K. A.
Format: Artigo
Langue:Inglês
Publié: 2008
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2664292/
https://ncbi.nlm.nih.gov/pubmed/18922005
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8018538
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