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Kinetic and Spectroscopic Studies of N694C Lipoxygenase: A Probe of the Substrate Activation Mechanism of a Non-Heme Ferric Enzyme
Lipoxygenases (LOs) comprise a class of substrate activating mononuclear non-heme iron enzymes which catalyze the hydroperoxidation of unsaturated fatty acids. A commonly proposed mechanism for LO catalysis involves H-atom abstraction by an Fe(III)-OH(-) site, best described as a proton coupled elec...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2896304/ https://ncbi.nlm.nih.gov/pubmed/17523638 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja068503d |
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