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Synthesis of an Acyltrifluoroborate and its Fusion with Azides to Form Amides

[Image: see text] A uniquely stable acyl potassium trifluoroborate, potassium (2-phenylacetyl) trifluoroborate, has been synthesized and isolated. In the presence of an activating Lewis acid, this reagent reacts with azides to form amides in good yields.

Tallennettuna:
Bibliografiset tiedot
Päätekijät: Molander, Gary A., Raushel, Jessica, Ellis, Noel M.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2010
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC2896291/
https://ncbi.nlm.nih.gov/pubmed/20481486
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo1004058
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