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Synthesis of Functionalized Organotrifluoroborates via the 1,3-Dipolar Cycloaddition of Azides
We have successfully prepared potassium azidoalkyltrifluoroborates from the corresponding halogen compounds in 94–98% yields through a nucleophilic substitution reaction with NaN(3). In the presence of various alkynes and CuI as a catalyst, these azidotrifluoroborates easily formed 1,4-disubstituted...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2515368/ https://ncbi.nlm.nih.gov/pubmed/16774252 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060826r |
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