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Probing static disorder in Arrhenius kinetics by single-molecule force spectroscopy
The widely used Arrhenius equation describes the kinetics of simple two-state reactions, with the implicit assumption of a single transition state with a well-defined activation energy barrier ΔE, as the rate-limiting step. However, it has become increasingly clear that the saddle point of the free-...
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| Main Authors: | , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2895103/ https://ncbi.nlm.nih.gov/pubmed/20534507 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1006517107 |
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