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Catalytic Nucleophilic Glyoxylation of Aldehydes
[Image: see text] β-Silyloxy-α-ketoesters are prepared through a cyanide-catalyzed benzoin-type reaction with silyl glyoxylates and aldehydes. The products undergo a dynamic kinetic resolution to provide enantioenriched orthogonally protected alcohols and can be converted to the corresponding β-sily...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2890213/ https://ncbi.nlm.nih.gov/pubmed/20481613 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100996w |
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