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Diastereoselective Synthesis of a Spironoraristeromycin Using an Acylnitroso Diels-Alder Reaction
[Image: see text] The tert-butyl N-hydroxycarbamate derived nitroso reagent 1 reacted with N-Cbz protected spirocyclic diene 2 to provide spirocycloadduct 3. Here we describe the efficient conversion of 3 into the novel carbocyclic nucleoside spironoraristeromycin 4.
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2888906/ https://ncbi.nlm.nih.gov/pubmed/19601571 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900877b |
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