Diastereoselective Synthesis of a Spironoraristeromycin Using an Acylnitroso Diels-Alder Reaction

[Image: see text] The tert-butyl N-hydroxycarbamate derived nitroso reagent 1 reacted with N-Cbz protected spirocyclic diene 2 to provide spirocycloadduct 3. Here we describe the efficient conversion of 3 into the novel carbocyclic nucleoside spironoraristeromycin 4.

Kaydedildi:
Detaylı Bibliyografya
Asıl Yazarlar: Lin, Weimin, Virga, Kristopher G., Kim, Kyung-Hee, Zajicek, Jaroslav, Mendel, David, Miller, Marvin J.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2009
Konular:
Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2888906/
https://ncbi.nlm.nih.gov/pubmed/19601571
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900877b
Etiketler: Etiketle
Etiket eklenmemiş, İlk siz ekleyin!

Benzer Materyaller