Diastereoselective Synthesis of a Spironoraristeromycin Using an Acylnitroso Diels-Alder Reaction

[Image: see text] The tert-butyl N-hydroxycarbamate derived nitroso reagent 1 reacted with N-Cbz protected spirocyclic diene 2 to provide spirocycloadduct 3. Here we describe the efficient conversion of 3 into the novel carbocyclic nucleoside spironoraristeromycin 4.

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Lin, Weimin, Virga, Kristopher G., Kim, Kyung-Hee, Zajicek, Jaroslav, Mendel, David, Miller, Marvin J.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2009
Gaiak:
Article
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2888906/
https://ncbi.nlm.nih.gov/pubmed/19601571
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900877b
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