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Chemoselective Protection of α-Ketoacids by Direct Annulations with Oximes
[Image: see text] Oximes and α-ketoacids undergo an unexpectedly facile and chemoselective annulation to afford 2,5-dihydrooxazole 3-oxides. The resulting cyclic nitrones serve as chemically and configurationally stable masked α-ketoacids that can be easily elaborated and manipulated. Deprotection i...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2883889/ https://ncbi.nlm.nih.gov/pubmed/20356071 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100467t |
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