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Superacid-Catalyzed Reactions of Olefinic Pyrazines: an Example of Anti-Markovnikov Addition Involving Superelectrophiles
[Figure: see text] Olefinic pyrazines are found to react with benzene in CF(3)SO(3)H and give anti-Markovnikov-type addition products. We propose that this is caused by two effects: destabilization of the carbocationic intermediates that would lead to Markovnikov-type products and the generation of...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2883295/ https://ncbi.nlm.nih.gov/pubmed/15932234 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol050900q |
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