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Superelectrophiles and the effects of trifluoromethyl substituents

[Image: see text] Trifluoromethyl-substituted superelectrophiles were generated in superacid (CF(3)SO(3)H) and their chemistry was examined. The strong electron withdrawing properties of the trifluoromethyl group are found to enhance the electrophilic character at cationic sites in superelectrophile...

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Detalhes bibliográficos
Main Authors: O'Connor, Matthew J., Boblak, Kenneth N., Topinka, Michael J., Kindelin, Patrick J., Briski, Jason M., Zheng, Chong, Klumpp, Douglas A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2883283/
https://ncbi.nlm.nih.gov/pubmed/20178387
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1001482
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