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Arenechromiumtricarbonyl complexes of silyl(germyl)(stannyl)- and silyl(germyl)(plumbyl)methanes including unexpected formation of arenechromiumtricarbonyldimethylsilanol, (η(6)-C(6)H(5))Cr(CO)(3)SiMe(2)OH
Treatment of PhMe(2)SiCH(2)GeMe(3) (1) with t-BuLi followed by addition of Me(3)ECl, E = Sn, Pb, results in the formation of phenylsilyl(germyl)stannyl- and phenylsilyl(germyl)plumbyl-methanes, PhMe(2)Si(Me(3)Ge)(EMe(3))CH, E = Sn (2), Pb (3). The thermal reaction of 1, 2 and 3 with Cr(CO)(6) yields...
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| Main Authors: | , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2010
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2883176/ https://ncbi.nlm.nih.gov/pubmed/20543962 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jorganchem.2010.01.027 |
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