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Formation of silicon-carbon bonds by photochemical irradiation of (η(5)-C(5)H(5))Fe(CO)(2)SiR(3) and (η(5)-C(5)H(5))Fe(CO)(2)Me to obtain R(3)SiMe
Photochemical irradiation of an equimolar mixture of (η(5)-C(5)H(5))Fe(CO)(2)SiR(3), FpSiR(3), and FpMe leads to the efficient formation of the silicon-carbon coupled product R(3)SiMe, R(3) = Me(3), Me(2)Ph, MePh(2), Ph(3), ClMe(2), Cl(2)Me, Cl(3), Me(2)Ar (Ar = C(6)H(4)X, X = F, OMe, CF(3), NMe(2)....
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2840652/ https://ncbi.nlm.nih.gov/pubmed/20305775 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om901114q |
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