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Enantioselective synthesis of bicylco[3.2.1]octan-8-ones using a tandem Michael-Henry reaction
Bicyclo[3.2.1]octan-8-ones have been prepared from a tandem Michael-Henry reaction between cyclohexane-1,2-diones and nitroalkenes using a quinine-derived thiourea as the catalyst. Although four stereogenic centers were created during the reaction, only two diastereomers were obtained in good diaste...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2010
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880813/ https://ncbi.nlm.nih.gov/pubmed/20532185 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2010.04.044 |
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