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Analysis of Kinetic Isotope Effects for Proton-Coupled Electron Transfer Reactions
A series of rate constant expressions for nonadiabatic proton-coupled electron transfer (PCET) reactions are analyzed and compared. The approximations underlying each expression are enumerated, and the regimes of validity for each expression are illustrated by calculations on model systems. In addit...
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| Asıl Yazarlar: | , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2009
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880663/ https://ncbi.nlm.nih.gov/pubmed/19182970 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp809122y |
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