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Strain-Release in C–H Bond Activation?

[Image: see text] What a relief! In 1955 the principle of strain release was put forward to explain the differing reactivity of axial and equitorial alcohols during oxidation. Our findings suggest that this same rationale may account for the differing rates of activation between axial and equitorial...

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Autors principals: Chen, Ke, Eschenmoser, Albert, Baran, Phil S.
Format: Artigo
Idioma:Inglês
Publicat: 2009
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2879134/
https://ncbi.nlm.nih.gov/pubmed/19937877
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200904474
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