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Scalable, Electrochemical Oxidation of Unactivated C–H Bonds

[Image: see text] A practical electrochemical oxidation of unactivated C–H bonds is presented. This reaction utilizes a simple redox mediator, quinuclidine, with inexpensive carbon and nickel electrodes to selectively functionalize “deep-seated” methylene and methine moieties. The process exhibits a...

詳細記述

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書誌詳細
出版年:J Am Chem Soc
主要な著者: Kawamata, Yu, Yan, Ming, Liu, Zhiqing, Bao, Deng-Hui, Chen, Jinshan, Starr, Jeremy T., Baran, Phil S.
フォーマット: Artigo
言語:Inglês
出版事項: American Chemical Society 2017
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5465511/
https://ncbi.nlm.nih.gov/pubmed/28510449
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03539
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