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Synthesis of Unsymmetrical ortho-Biphenols and ortho-Binaphthols via Silicon-Tethered Pd-Catalyzed C–H Arylation

[Image: see text] A mild, practical, and efficient method for the synthesis of unsymmetrical ortho-biphenols (including ortho-phenol-naphthols and ortho-binaphthols) has been developed. Unsymmetrical bis-aryloxy silanes, which were readily prepared in a semi-one-pot fashion, underwent the Pd-catalyz...

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Hlavní autoři: Huang, Chunhui, Gevorgyan, Vladimir
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2873232/
https://ncbi.nlm.nih.gov/pubmed/20423110
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100924n
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