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Concerted O atom–proton transfer in the O—O bond forming step in water oxidation

As the terminal step in photosystem II, and a potential half-reaction for artificial photosynthesis, water oxidation (2H(2)O → O(2) + 4e(-) + 4H(+)) is key, but it imposes a significant mechanistic challenge with requirements for both 4e(-)/4H(+) loss and O—O bond formation. Significant progress in...

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Main Authors: Chen, Zuofeng, Concepcion, Javier J., Hu, Xiangqian, Yang, Weitao, Hoertz, Paul G., Meyer, Thomas J.
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2867729/
https://ncbi.nlm.nih.gov/pubmed/20360565
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1001132107
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