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2D-IR Experiments and Simulations of the coupling between amide-I and ionizable side chains in proteins: Application to the Villin headpiece

The carboxylate side chains of Asp and Glu have significant coupling with the amide states of the backbone of Villin headpiece. In two dimensional spectroscopy, cross peaks are observed between these side chains and the main amide-I band. To model the absorption of the side chains, the electric fiel...

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書目詳細資料
Main Authors: Bagchi, Sayan, Falvo, Cyril, Mukamel, Shaul, Hochstrasser, Robin M.
格式: Artigo
語言:Inglês
出版: 2009
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2861833/
https://ncbi.nlm.nih.gov/pubmed/19618902
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp900245s
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