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Vibrational Analysis of the Model Complex (μ-edt)[Fe(CO)(3)](2) and Comparison to Iron-only Hydrogenase: The Activation Scale of Hydrogenase Model Systems

Research on simple [FeFe] hydrogenase model systems of type (μ-S(2)R)[Fe(CO)(3)](2) (R = ethane, propane) which have been shown to function as robust electrocatalysts for proton reduction, provides a reference to understand the electronic and vibrational properties of the active site of [FeFe] hydro...

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Detalhes bibliográficos
Main Authors: Galinato, Mary Grace I., Whaley, C. Matthew, Lehnert, Nicolai
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2860110/
https://ncbi.nlm.nih.gov/pubmed/20225804
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic9022135
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