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Palladium- and Nickel-Catalyzed Carbon–Carbon Bond Insertion Reactions with Alkylidenesilacyclopropanes

Palladium and nickel catalysts promoted highly selective carbon–carbon bond insertion reactions with di-tert-butyl-alkylidenesilacyclopropanes. Pd(PPh(3))(4) was demonstrated to be the optimal catalyst, allowing for a variety of carbon–carbon π-bond insertion reactions. Depending on the nature of th...

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Autori principali: Buchner, Kay M., Woerpel, K. A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2856941/
https://ncbi.nlm.nih.gov/pubmed/20419110
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om901042j
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