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Asymmetric Total Synthesis of Vindoline

A concise asymmetric total synthesis of (−)-vindoline (1) is detailed based on a tandem intramolecular [4+2]/[3+2] cycloaddition cascade of a 1,3,4-oxadiazole inspired by the natural product structure, in which the tether linking the initiating dienophile and oxadiazole bears a chiral substituent th...

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Bibliografski detalji
Glavni autori: Kato, Daisuke, Sasaki, Yoshikazu, Boger, Dale L.
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2854892/
https://ncbi.nlm.nih.gov/pubmed/20187641
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910695e
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