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Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation

Chemical reactions that involve net hydrogen atom transfer (HAT) are ubiquitous in chemistry and biology, from the action of antioxidants to industrial and metalloenzyme catalysis. This report develops and validates a procedure to predict rate constants for HAT reactions of oxyl radicals (RO(•)) in...

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Detalles Bibliográficos
Autores principales: Warren, Jeffrey J., Mayer, James M.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2010
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2851756/
https://ncbi.nlm.nih.gov/pubmed/20215463
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0910347107
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