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Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation
Chemical reactions that involve net hydrogen atom transfer (HAT) are ubiquitous in chemistry and biology, from the action of antioxidants to industrial and metalloenzyme catalysis. This report develops and validates a procedure to predict rate constants for HAT reactions of oxyl radicals (RO(•)) in...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2851756/ https://ncbi.nlm.nih.gov/pubmed/20215463 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0910347107 |
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