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Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation

Chemical reactions that involve net hydrogen atom transfer (HAT) are ubiquitous in chemistry and biology, from the action of antioxidants to industrial and metalloenzyme catalysis. This report develops and validates a procedure to predict rate constants for HAT reactions of oxyl radicals (RO(•)) in...

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Hlavní autoři: Warren, Jeffrey J., Mayer, James M.
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2851756/
https://ncbi.nlm.nih.gov/pubmed/20215463
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0910347107
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