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Cu(i) recognition via cation-π and methionine interactions in CusF
Methionine-rich motifs have an important role in copper trafficking factors, including the CusF protein. Here we show that CusF uses a new metal recognition site wherein Cu(i) is tetragonally displaced from a Met(2)His ligand plane toward a conserved tryptophan. Spectroscopic studies demonstrate tha...
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| Main Authors: | , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2850561/ https://ncbi.nlm.nih.gov/pubmed/18157124 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchembio.2007.57 |
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