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Efficient methodology for alkylation of vinylnitroso compounds with carbon nucleophiles
A diverse array of nitrosoalkenes derived from both acyclic and cyclic ketones, as well as aldehydes, via the Denmark protocol using α-chloro-O-TBS-oximes can be trapped efficiently in situ by a wide variety of potassium ester enolates to afford conjugate addition products in good yields.
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2850119/ https://ncbi.nlm.nih.gov/pubmed/20383272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.02.050 |
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