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A mild, efficient method for the oxidation of α-diazo-β-hydroxyesters to α-diazo-β-ketoesters
A wide variety of α-diazo-β-ketoesters can be prepared in good overall yields via a two-step sequence involving addition of ethyl lithiodiazoacetate to aliphatic, aromatic and conjugated aldehydes followed by mild oxidation with the Dess-Martin periodinane.
में बचाया:
| मुख्य लेखकों: | , , , |
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| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
2008
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2390928/ https://ncbi.nlm.nih.gov/pubmed/19421308 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.03.011 |
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