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A mild, efficient method for the oxidation of α-diazo-β-hydroxyesters to α-diazo-β-ketoesters

A wide variety of α-diazo-β-ketoesters can be prepared in good overall yields via a two-step sequence involving addition of ethyl lithiodiazoacetate to aliphatic, aromatic and conjugated aldehydes followed by mild oxidation with the Dess-Martin periodinane.

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Podrobná bibliografie
Hlavní autoři: Li, Puhui, Majireck, Max M., Korboukh, Ilia, Weinreb, Steven M.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2390928/
https://ncbi.nlm.nih.gov/pubmed/19421308
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.03.011
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