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Stereochemical investigation of conjugate additions of carbon- and heteronucleophiles to ring-substituted nitrosocyclohexenes

Intermolecular Michael-type conjugate additions of some in situ-generated ring-substituted nitrosocyclohexenes with both carbon- and heteronucleophiles have been found to be highly stereoselective, leading predominantly (or exclusively) to products resulting from axial attack on a half-chair conform...

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Detalhes bibliográficos
Main Authors: Sengupta, Ritobroto, Witek, Jason A., Weinreb, Steven M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3224044/
https://ncbi.nlm.nih.gov/pubmed/22125343
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.08.054
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