anti-Diastereo- and Enantioselective Carbonyl (Hydroxymethyl)allylation from the Alcohol or Aldehyde Oxidation Level: Allyl Carbonates as Allylmetal Surrogates

[Image: see text] Enantioselective transfer hydrogenation of carbonate 1a in the presence of aromatic, allylic or aliphatic alcohols 2a–2i employing a cyclometallated iridium C,O-benzoate derived from allyl acetate, 4-cyano-3-nitrobenzoic acid and (S)-SEGPHOS delivers products of (hydroxymethyl)ally...

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Bibliografische gegevens
Hoofdauteurs: Zhang, Yong Jian, Yang, Jin Haek, Kim, Sang Hoon, Krische, Michael J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2010
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Article
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2848290/
https://ncbi.nlm.nih.gov/pubmed/20225853
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja100949e
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