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Amide-Directed Catalytic Asymmetric Hydroboration of Trisubstituted Alkenes

[Image: see text] Rhodium-catalyzed hydroborations of trisubstituted alkenes are generally slow and often suffer from competing alkene isomerization. In contrast, the trisubstituted alkene moieties contained within the framework of a β,γ-unsaturated amide undergo facile reaction, perhaps facilitated...

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Hlavní autoři: Smith, Sean M., Takacs, James M.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2846594/
https://ncbi.nlm.nih.gov/pubmed/20092272
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja908257x
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