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Insight into the mechanism of an iron dioxygenase by resolution of steps following the Fe(IV)═O species
Iron oxygenases generate elusive transient oxygen species to catalyze substrate oxygenation in a wide range of metabolic processes. Here we resolve the reaction sequence and structures of such intermediates for the archetypal non-heme Fe(II) and α-ketoglutarate-dependent dioxygenase TauD. Time-resol...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2840172/ https://ncbi.nlm.nih.gov/pubmed/20147623 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0911565107 |
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