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Application of the Chloro Ketal Claisen Reaction to the Total Synthesis of Squalene
A short, highly stereoselective (over 97%) synthesis of all-trans squalene is described. Starting with succinaldehyde, a tetraenedichlorodione having the complete squalene skeleton with the four internal trans olefinic bonds has been developed in four steps involving a sequence of two double Claisen...
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| Udgivet i: | Proc Natl Acad Sci U S A |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
1970
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC283375/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/5274470/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.67.3.1465 |
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