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A Short Stereoselective Synthesis of Cecropia Juvenile Hormone

A very short synthesis of the racemic cecropia hormone has been realized, utilizing a Claisen reaction. Methyl 6-hydroxy-3-methyl-7-methylene-2-trans-nonenoate, on treatment with the dimethyl ketal of 3-chloro-3-methyl-2-pentanone and a catalytic amount of 2,4-dinitrophenol, is transformed directly...

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Hlavní autoři: Loew, Peter, Siddall, John B., Spain, Virginia L., Werthemann, Lucius
Médium: Artigo
Jazyk:Inglês
Vydáno: 1970
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC283374/
https://ncbi.nlm.nih.gov/pubmed/5274469
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