TOTAL SYNTHESIS OF THE RACEMIC FORM OF THE SECOND JUVENILE HORMONE (METHYL 12-HOMOJUVENATE) FROM THE CECROPIA SILK MOTH

Methyl cis-10-epoxy-3,7,11-trimethyl-trans,trans-2,6-tridecadienoate has been stereoselectively synthesized in 12 steps starting from methyl trans-γ-bromo-β,β-dimethylacrylate and 1-acetyl-1-methylcyclopropane. The final product proved to be identical with the second, less abundant juvenile hormone...

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Pubblicato in:	Proc Natl Acad Sci U S A
Autori principali:	Johnson, William S., Campbell, Simon F., Krishnakumaran, A., Meyer, Andre S.
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	National Academy of Sciences 1969
Soggetti:	Physical Sciences: Chemistry
Accesso online:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC223604/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16591739/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.62.4.1005
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