TOTAL SYNTHESIS OF THE RACEMIC FORM OF THE SECOND JUVENILE HORMONE (METHYL 12-HOMOJUVENATE) FROM THE CECROPIA SILK MOTH

Methyl cis-10-epoxy-3,7,11-trimethyl-trans,trans-2,6-tridecadienoate has been stereoselectively synthesized in 12 steps starting from methyl trans-γ-bromo-β,β-dimethylacrylate and 1-acetyl-1-methylcyclopropane. The final product proved to be identical with the second, less abundant juvenile hormone...

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Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Johnson, William S., Campbell, Simon F., Krishnakumaran, A., Meyer, Andre S.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 1969
Gaiak:
Physical Sciences: Chemistry
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC223604/
https://ncbi.nlm.nih.gov/pubmed/16591739
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