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Application of germyldesulfonylation reactions to the synthesis of germanium-containing nucleoside analogues

Treatment of the protected (E)-5′-deoxy-5′-[(p-toluenesulfonyl)methylene]uridine and adenosine derivatives with tributyl- or triphenylgermane hydride (AIBN/toluene/Δ) effected radical-mediated germyldesulfonylations to give 5′-(tributyl- or triphenylgermyl)methylene-5′-deoxyuridine and adenosine der...

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Detalhes bibliográficos
Main Authors: Wnuk, Stanislaw F., Sacasa, Pablo R., Restrepo, Jorge
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2829740/
https://ncbi.nlm.nih.gov/pubmed/20183601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/15257770903054340
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