Loading...
Structure-Reactivity Effects on Primary Deuterium Isotope Effects on Protonation of Ring-Substituted α-Methoxystyrenes
Primary product isotope effects (PIEs) on L(+)- and carboxylic acid-catalyzed protonation of ring-substituted α-methoxystyrenes (X-1) to form oxocarbenium ions X-2(+) in 50/50 (v/v) HOH/DOD were calculated from the yields of the α-CH(3) and α-CH(2)D labeled ketone products, determined by (1)H NMR. A...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2009
|
| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2825562/ https://ncbi.nlm.nih.gov/pubmed/19788330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja905080e |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|