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Structure-Reactivity Effects on Primary Deuterium Isotope Effects on Protonation of Ring-Substituted α-Methoxystyrenes
Primary product isotope effects (PIEs) on L(+)- and carboxylic acid-catalyzed protonation of ring-substituted α-methoxystyrenes (X-1) to form oxocarbenium ions X-2(+) in 50/50 (v/v) HOH/DOD were calculated from the yields of the α-CH(3) and α-CH(2)D labeled ketone products, determined by (1)H NMR. A...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2825562/ https://ncbi.nlm.nih.gov/pubmed/19788330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja905080e |
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