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O-Acylation of Hydroxyproline Residues: Effect on Peptide Bond Isomerization and Collagen Stability

In collagen, strands of sequence XaaYaaGly form a triple helical structure. The Yaa residue is often (2S,4R)-4-hydroxyproline (Hyp). The inductive effect of the hydroxyl group of Hyp residues greatly increases collagen stability. Here, electron withdrawal by the hydroxyl group in Hyp and its 4S dias...

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Detalhes bibliográficos
Main Authors: Jenkins, Cara L., McCloskey, Alexander I., Guzei, Ilia A., Eberhardt, Eric S., Raines, Ronald T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2824568/
https://ncbi.nlm.nih.gov/pubmed/15558658
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/bip.20164
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