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The Modular Nature of All-Ferrous Edge-Bridged Double Cubanes

Two all-ferrous, edge-bridged 8Fe−8S clusters, one capped with carbenes (2) the other with phosphenes (3), have been characterized by (57)Fe Mössbauer spectroscopy. The clusters have diamagnetic ground states that yield spectra consisting of one quadrupole doublet with a large splitting (25% of abso...

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Autors principals: Chakrabarti, Mrinmoy, Deng, Liang, Holm, R. H., Münck, Eckard, Bominaar, Emile L.
Format: Artigo
Idioma:Inglês
Publicat: 2010
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2822436/
https://ncbi.nlm.nih.gov/pubmed/20073485
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic902050k
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